In this paper we report the first use of Al(III) salalen complexes for the ring opening polymerisation of rac-lactide. Polylactides with narrow polydispersities (PDIs range from 1.04–1.65) and moderate degrees of stereoselectivity were formed. Eight salalen Al(III) complexes have been prepared and fully characterised by solution-state NMR spectroscopy and, where appropriate, single crystal X-ray diffraction. With ligand 3H₂ either a monomeric or dimeric Al(III) species was formed, the dimeric species was favoured at low concentrations. The complexes were tested for the ring opening polymerisation of rac-lactide in toluene at 80 or 100 °C. Interestingly, various tacticities of polymer were formed, which were dependent upon the nature of the group bound to the amine nitrogen centre.