Synthesis of optically pure [60]fullerene e,e,e-tris adducts†‡,10.1039/C3CC41409D

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Synthesis of optically pure [60]fullerene e,e,e-tris adducts†‡

Sebastiano Guerra,Franck Schillinger,David Sigwalt,Michel Holler,Jean-François Nierengarten

Chemical Communications Pub Date : 04/19/2013 00:00:00 , DOI:10.1039/C3CC41409D

Abstract

The reaction of readily available optically active Si-tethered tris(malonates) with C₆₀ gave easily separable diastereoisomers differing by the absolute configuration of the inherently chiral addition pattern on the fullerene core. The absolute configuration of the e,e,e addition pattern has been unambiguously determined using X-ray crystal structure analysis.