Synthesis of polypeptide based rod–coil block copolymers†
Simone Steig,Frauke Cornelius,Peter Witte,Bastiaan B. P. Staal,Cor E. Koning,Andreas Heise,Henning Menzel
Chemical Communications Pub Date : 09/30/2005 00:00:00 , DOI:10.1039/B510644C
Abstract
A bifunctional initiator was synthesized and used for a sequence of a nickel initiated polymerization of γ-benzyl-L-glutamate-N-carboxy anhydride and atom transfer radical polymerization of methyl methacrylate yielding a rod–coil block copolymer.