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Secondary coordination sphere controlled reversible geometry reorganisations in copper(ii) complexes†
John Fielden,De-Liang Long,Leroy Cronin
Chemical Communications Pub Date : 08/20/2004 00:00:00 , DOI:10.1039/B407229D
Abstract

Reversible geometry reorganisations are demonstrated by cis-3,5-diamino-trans-hydroxycyclohexane (cis,trans-DAHC) copper(II) fluoride complexes, with the concentration of water in the mother liquor controlling interconversion between blue crystals of 5-coordinate syn-[Cu(DAHC)2F](F)·2CH3OH·H2O and red crystals of 4-coordinate anti-[Cu(DAHC)2](F)2·2H2O.

Graphical abstract: Secondary coordination sphere controlled reversible geometry reorganisations in copper(ii) complexes
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