Herein, we describe a soluble iron(II)-phthalocyanine, [Fe^II(^tBu₄Pc)(py)₂] (Pc = phthalocyaninato(2–)), as an effective catalyst in intramolecular C(sp³)–H bond amination, with alkyl azides as the nitrogen source, to afford the amination products in moderate to excellent yields with a broad substrate scope.