A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group†,10.1039/C4DT00327F

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group†

Alexandre Abhervé,Miguel Clemente-León,Eugenio Coronado,Carlos J. Gómez-García,Maurici López-Jordà

Dalton Transactions Pub Date : 03/17/2014 00:00:00 , DOI:10.1039/C4DT00327F

Abstract

Combining Fe(II) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl)pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)₂](ClO₄)₂ which shows an abrupt spin transition with a T_1/2 of ca. 380 K and a T_LIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.