Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes†,10.1039/C4DT02159B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes†

Takako Muraoka,Keisuke Abe,Haruhiko Kimura,Youhei Haga,Keiji Ueno,Yusuke Sunada

Dalton Transactions Pub Date : 09/23/2014 00:00:00 , DOI:10.1039/C4DT02159B

Abstract

Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the M [double bond, length as m-dash] Si bond in the silyl(silylene)molybdenum complex with 1 eq. of PNO in the presence of Lewis base L. The PNO-coordinated silanone complex (L = PNO) was converted to cis-[Cp*(OC)₂Mo{OSiMes₂(OSiMe₃)}(PMe₃)] in the presence of excess PMe₃.