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Synthetic studies toward the marine metabolite prorocentin-4: synthesis of the C1–C23 fragment†
Praveen AnkiReddy,Sandeep AnkiReddy,Sabitha Gowravaram
Organic & Biomolecular Chemistry Pub Date : 05/10/2018 00:00:00 , DOI:10.1039/C8OB00388B
Abstract

A synthetic study of the construction of the C1–C23 fragment of prorocentin-4, a novel linear polyketide, is described. The synthetic highlights include the acid catalyzed epoxide opening, Gilman reaction, Pd(OH)2 catalyzed transformation of a primary propargylic alcohol into an aldehyde, Oxa-Michael cyclization, and Horner–Wadsworth–Emmons (HWE) olefination reaction as key steps.

Graphical abstract: Synthetic studies toward the marine metabolite prorocentin-4: synthesis of the C1–C23 fragment
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