Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis†,10.1039/C4SC00885E

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis†

Mathew D. Anker,Merle Arrowsmith,Peter Bellham,Michael S. Hill,Gabriele Kociok-Köhn,David J. Liptrot,Mary F. Mahon,Catherine Weetman

Chemical Science Pub Date : 04/24/2014 00:00:00 , DOI:10.1039/C4SC00885E

Abstract

Treatment of β-diketiminato Mg and Ca amidoborane compounds with B(C₆F₅)₃ induces hydride elimination and formation of alkaline earth hydrido-tris(pentafluorophenyl)borate derivatives. Both species react with CO₂ to provide formate complexes, one of which has been structurally characterised, and may be applied to the highly selective reductive hydroboration of CO₂ with pinacolborane (HBpin) to provide the methanol equivalent, CH₃OBpin.