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Selective colorimetric sensing of Co(ii) in aqueous media with a spiropyran–amide–dipicolylamine linkage under UV irradiation†
Yasuhiro Shiraishi,Yoshinao Matsunaga,Takayuki Hirai
Chemical Communications Pub Date : 04/12/2012 00:00:00 , DOI:10.1039/C2CC30258F
Abstract

A spiropyran–amide–dipicolylamine linkage behaves as a colorimetric receptor for selective Co2+ sensing in aqueous media under UV irradiation. This is promoted by strong coordination of Co2+ with amide oxygens of the receptors and efficient photoisomerization of the spiropyran moieties.

Graphical abstract: Selective colorimetric sensing of Co(ii) in aqueous media with a spiropyran–amide–dipicolylamine linkage under UV irradiation
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