960化工网
Selective production of indane and its derivatives from lignin over a modified niobium-based catalyst†
Yu Xin,Yaxuan Jing,Lin Dong,Xiaohui Liu,Yong Guo,Yanqin Wang
Chemical Communications Pub Date : 07/09/2019 00:00:00 , DOI:10.1039/C9CC04101J
Abstract

Starting from native lignin, the first example of the efficient production of indane and its derivatives was achieved over a CH2Cl2-modified Ru/Nb2O5 catalyst. Intensive characterization reveals that CH2Cl2 weakens the hydrogenolysis ability of Ru particles through the strong interaction between CH2Cl2 and Ru, and promotes the intramolecular cyclization reaction.

Graphical abstract: Selective production of indane and its derivatives from lignin over a modified niobium-based catalyst
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