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Stereoselective synthesis of Jaspine B and its C2 epimer from Garner aldehyde†
Amit Kumar Jana,Gautam Panda
RSC Advances Pub Date : 07/16/2013 00:00:00 , DOI:10.1039/C3RA41778F
Abstract

Two different stereoselective routes for the synthesis of Jaspine B and its C2 epimer are presented here, starting from easily available Garner aldehyde. The key synthetic steps involved iodocyclization, organocuprate addition, HWE olefination, regioselective α-tosylation and cross metathesis reaction. This is the first report to synthesize Jaspine B involving iodocyclization.

Graphical abstract: Stereoselective synthesis of Jaspine B and its C2 epimer from Garner aldehyde
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