Steric constraint generating large through-space
1H–203,205Tl coupling in a
dithallium(I) cryptate
Jane Nelson,Vickie McKee
Chemical Communications Pub Date : 01/07/2000 00:00:00 , DOI:10.1039/A908476B
Abstract
An aminocryptand host enforces approach of encapsulated Tl(I) ions to just within 4.4 Å; despite this relatively large separation, strong Tl(I)⋯Tl(I) interaction is observed and the aromatic proton of the bridging link exhibits a large through-space coupling to the pair of equivalent Tl nuclei.
