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Through-space conjugated polymers consisting of [2.2]paracyclophane
Yasuhiro Morisaki,Yoshiki Chujo
Polymer Chemistry Pub Date : 03/04/2011 00:00:00 , DOI:10.1039/C0PY00421A
Abstract

In this review, the synthesis and fundamental properties of [2.2]paracyclophane-containing through-space conjugated polymers are introduced. By incorporating pseudo-para-, pseudo-ortho-, and pseudo-geminal-linked [2.2]paracyclophane skeletons into conjugated polymer backbones, through-space conjugated polymers consisting of stacked π-electron systems can be prepared. Recent reports in the last two years are especially focused on conjugated polymers, and the characteristic features of the through-space conjugated polymers constructed by [2.2]paracyclophane are reviewed.

Graphical abstract: Through-space conjugated polymers consisting of [2.2]paracyclophane
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