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Semiconducting alternating multi-block copolymers via a di-functionalized macromonomer approach†
A. Gasperini,M. Johnson,X. Jeanbourquin,L. Yao,A. Rahmanudin,N. Guijarro,K. Sivula
Polymer Chemistry Pub Date : 01/03/2017 00:00:00 , DOI:10.1039/C6PY01921H
Abstract

The development of fully-conjugated semiconducting block-copolymers is an important goal for organic electronics, but to date has been almost exclusively limited to materials containing poly(3-alkylthiophenes). Here we present the prototype of a class of fully-conjugated semiconducting block copolymers (prepared using a versatile route based on conjugated macromonomers and a cross-coupling polycondensation) that exhibit hole mobility in field effect transistors of the order of 0.1 cm2 V−1 s−1 and nanoscopic phase domain separation.

Graphical abstract: Semiconducting alternating multi-block copolymers via a di-functionalized macromonomer approach
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