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Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes†
Jack M. Carraher,Andreja Bakac
Chemical Communications Pub Date : 05/30/2013 00:00:00 , DOI:10.1039/C3CC43472A
Abstract

Macrocyclic rhodium(II) complexes LRh(H2O)2+ react with (dmgH)2(H2O)CoR and with (H2O)5CrR2+ by alkyl transfer for R = CH3 to generate L(H2O)RhCH32+. When R = C2H5, C3H7 or C4H9, the reaction takes place by hydrogen atom abstraction from the coordinated alkyl and produces L(H2O)RhH2+ and an α-olefin.

Graphical abstract: Alkyl group versus hydrogen atom transfer from metal alkyls to macrocyclic rhodium complexes
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