The first structurally characterised homoleptic σ-organotitanium(iii) compound
Pablo J. Alonso,Juan Forniés,M. Angeles García-Monforte,Antonio Martín,Babil Menjón
Chemical Communications Pub Date : 03/08/2002 00:00:00 , DOI:10.1039/B111127B
Abstract
The paramagnetic [EPR, S = 1/2, d1; gav = 1.959(2)] organotitanate(III) anion [TiIII(C6Cl5)4]− has been found to be a mononuclear species with nearly tetrahedral geometry (X-ray).