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Activation of olefins with low-valent gallium compounds under ambient conditions†
Christine A. Caputo,Zhongliang Zhu,Zachary D. Brown,James C. Fettinger,Philip P. Power
Chemical Communications Pub Date : 05/31/2011 00:00:00 , DOI:10.1039/C1CC11676B
Abstract

The reactions of Ar′GaGaAr′ (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2) with alkenes revealed the addition of two olefins per Ar′GaGaAr′ under ambient conditions for ethylene, propene, 1-hexene and styrene but no reactions with more hindered or cyclic olefins.

Graphical abstract: Activation of olefins with low-valent gallium compounds under ambient conditions
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