Tris(triphenylplumbyl)plumbate: an anion with three stretched lead–lead bonds,10.1039/B305217F

批量搜索

批量搜索

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Tris(triphenylplumbyl)plumbate: an anion with three stretched lead–lead bonds

Frank Stabenow,Wolfang Saak,Manfred Weidenbruch

Chemical Communications Pub Date : 08/11/2003 00:00:00 , DOI:10.1039/B305217F

Abstract

Treatment of lead(II) bromide with phenylmagnesium bromide at low temperature furnishes yellow crystals of the ionic compound [BrMg(THF)₅]⁺ [:Pb(PbPh₃)₃]⁻ which, upon X-ray crystallographic analysis, reveals three stretched Pb–Pb bonds and Pb–Pb–Pb angles of about 93°.