Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule†,10.1039/C8CC07886F

热搜：

Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Size-selective encapsulation of C60 and C60-derivatives within an adaptable naphthalene-based tetragonal prismatic supramolecular nanocapsule†

Cristina García-Simón,Alba Monferrer,Marc Garcia-Borràs,Inhar Imaz,Miquel Costas,Xavi Ribas

Chemical Communications Pub Date : 12/12/2018 00:00:00 , DOI:10.1039/C8CC07886F

Abstract

A novel naphthalene-based 5·(BArF)₈ capsule allows for the size-selective inclusion of C₆₀ from fullerene mixtures. Its size selectivity towards C₆₀ has been rationalized by its dynamic adaptability in solution that has been investigated by molecular dynamics. Additionally, 5·(BArF)₈ encapsulates C₆₀-derivatives such as C₆₀-PCBM and N-methylpyrrolidine-C₆₀. The latter can be separated from C₆₀ since 5·(BArF)₈ displays distinct affinity for them.