The Pauson–Khand reaction using alkynylboronic esters: solving a long-standing regioselectivity issue†
Thierry León,Elena Fernández
Chemical Communications Pub Date : 06/24/2016 00:00:00 , DOI:10.1039/C6CC04717C
Abstract
The first intermolecular Pauson–Khand reaction, conducted using internal alkynylboronic esters, allows the installation of the boronic ester moiety at the β-position of the cyclopentenone with total regio- and stereoselectivity.
