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Substituent effect on fluorophores instead of ionophores: its implication in highly selective fluorescent probes for Zn2+ over Cd2+†
Yongqian Xu,Liangliang Xiao,Yunfei Zhang,Shiguo Sun,Yi Pang
RSC Advances Pub Date : 12/10/2013 00:00:00 , DOI:10.1039/C3RA46468G
Abstract

Three fluorescent molecules with different substituent modification on 5-position showing different extents of fluorescent response to Zn2+ and distinct discriminating effect of RZn/RCd have been readily synthesized. The addition of a dithiol group induces the discriminating effect of RZn/RCd to be obviously improved from twice to 32 times.

Graphical abstract: Substituent effect on fluorophores instead of ionophores: its implication in highly selective fluorescent probes for Zn2+ over Cd2+
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