Solid-state solvolysis induced via charge-transfer complexation by solid-phase grinding followed by contact with solvent vapor
Chemical Communications Pub Date : 01/01/1900 00:00:00 , DOI:10.1039/A803496F
Abstract
When 9-thienothienylfluoren-9-ol derivatives were ground together with DDQ then exposed to methanol vapor, solvolysis occurred to yield 9-methoxyfluorenes via the generation of a radical cation by solid-state single-electron transfer.