Unusual salt effect on the lower critical solution temperature of hyperbranched thermoresponsive polymers†
Xunyong Liu,Fa Cheng,Huaji Liu
Soft Matter Pub Date : 08/01/2008 00:00:00 , DOI:10.1039/B811012N
Abstract

Compared with linear thermoresponsive polymers hyperbranched ones having spheroid-like structure exhibited an unusual salt effect: a non-linear LCST decrease upon increasing the concentration of various salts such as NaCl, KCl or Na2SO4 has been observed. The LCST variation of such polymers was more sensitive to the presence of salt.

Graphical abstract: Unusual salt effect on the lower critical solution temperature of hyperbranched thermoresponsive polymers