Through-space conjugated polymers consisting of planar chiral pseudo-ortho-linked [2.2]paracyclophane†,10.1039/C2PY20530K

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Through-space conjugated polymers consisting of planar chiral pseudo-ortho-linked [2.2]paracyclophane†

Yasuhiro Morisaki,Ryoyu Hifumi,Lin Lin,Kenichi Inoshita,Yoshiki Chujo

Polymer Chemistry Pub Date : 08/13/2012 00:00:00 , DOI:10.1039/C2PY20530K

Abstract

Herein, we describe the synthesis and chiroptical properties of through-space conjugated polymers with enantiopure planar chiral (R)- and (S)-pseudo-ortho-disubstituted [2.2]paracyclophane skeletons. The polymers exhibited intense circularly polarized luminescence in dilute solutions due to their conformationally stable planar chiral zigzag structures.