Stereoelectronic control of photophysics: red and yellow axial and equatorial anomers of a rhenium-quinoline complex†
Rachel H. Platel,Michael P. Coogan,James A. Platts
Dalton Transactions Pub Date : 06/10/2015 00:00:00 , DOI:10.1039/C5DT02136G
Abstract
A novel quinoline-substituted pyrimidine ligand forms two different coloured complexes upon reaction with Re(CO)5Br. These compounds display distinct photophysical properties that are dictated by their stereochemistry.