Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2†,10.1039/C3CE41332B

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Alternative synthetic methodology for amide formation in the post-synthetic modification of Ti-MIL125-NH2†

Adam P. Smalley,David G. Reid,Jin Chong Tan,Gareth O. Lloyd

CrystEngComm Pub Date : 09/02/2013 00:00:00 , DOI:10.1039/C3CE41332B

Abstract

There are relatively few metal–organic framework materials that are robust enough to survive post-synthetic modification of their structures. We present test modifications of Ti-MIL125-NH₂ leading towards tuning of the porous and catalytic properties of the material. We also present the first use of a mild amide synthesis method for post-synthetic modification.