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Stereospecificity in the silicon tethered α-(methyl)allylation of aldehydes†
Jeremy Robertson,Michael J. Hall,Stuart P. Green
Organic & Biomolecular Chemistry Pub Date : 09/03/2003 00:00:00 , DOI:10.1039/B306920F
Abstract

Heating E- and Z-crotyl(diphenyl)silyloxy aldehydes, in the absence of an added catalyst, results in stereospecific intramolecular allyl transfer with moderate to high stereoselectivity.

Graphical abstract: Stereospecificity in the silicon tethered α-(methyl)allylation of aldehydes
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