Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids†
Jun-ichiro Setsune,Masayuki Toda,Takafumi Yoshida
Chemical Communications Pub Date : 02/19/2008 00:00:00 , DOI:10.1039/B717022J
Abstract
Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.
