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Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors†
Alison J. Cross,Matthew G. Davidson,Daniel García-Vivó,Tony D. James
RSC Advances Pub Date : 05/04/2012 00:00:00 , DOI:10.1039/C2RA20373A
Abstract

We report the controlled synthesis of boronic-acid terminated polylactides via the use of a protected boronic acid-functionalised ring-opening polymerisation initiator and the subsequent deprotection of the resultant polymer. We have demonstrated the utility of this approach to biocompatible polymer conjugates of biologically-relevant diols using an indicator-displacement assay.

Graphical abstract: Well-controlled synthesis of boronic-acid functionalised poly(lactide)s: a versatile platform for biocompatible polymer conjugates and sensors
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