Synthesis of a model DEF-ring core of hexacyclinic acid†
Paul A. Clarke,Matthew Grist,Mark Ebden,Claire Wilson
Chemical Communications Pub Date : 06/03/2003 00:00:00 , DOI:10.1039/B303706A
Abstract
The first synthesis of a DEF-ring system of hexacyclinic acid is reported. The key steps being an intramolecular Pd(0) π-allyl substitution reaction, followed by a transannular iodocyclisation with acetyl hypoiodite.
