Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study†
Samya Banerjee,Sayan Dutta,Samir Kumar Sarkar,Nico Graw,Regine Herbst-Irmer,Debasis Koley,Dietmar Stalke,Herbert W. Roesky
Dalton Transactions Pub Date : 10/01/2020 00:00:00 , DOI:10.1039/D0DT03161E
Abstract

Synthesis and bonding aspects of mononuclear bis-amidinate indium(III) monohalides L2InX (1–3), where L = PhC(NtBu)2; X is F (1), Br (2) or I (3) and β-diketiminate (NacNac) stabilized In(II) dimer (MesNacNac)2In2Br2 (4) with In–In bond are reported along with the single-crystal X-ray structures of 2–4.

Graphical abstract: Amidinate based indium(iii) monohalides and β-diketiminate stabilized In(ii)–In(ii) bond: synthesis, crystal structure, and computational study