Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3†
Robert J. Less,Hayley R. Simmonds,Sarah B. J. Dane,Dominic S. Wright
Dalton Transactions Pub Date : 12/18/2012 00:00:00 , DOI:10.1039/C2DT32569A
Abstract
Structural and in situNMR spectroscopic studies show that N–H deprotonation, B–N bond cleavage and B–N bond formation can occur in the stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3.