Aerobic oxidation and oxidative esterification of alcohols through cooperative catalysis under metal-free conditions†,10.1039/D1CC02937A

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Aerobic oxidation and oxidative esterification of alcohols through cooperative catalysis under metal-free conditions†

Mina Ghahremani,Hojatollah Vali,Rosaria Ciriminna,Mario Pagliaro

Chemical Communications Pub Date : 08/09/2021 00:00:00 , DOI:10.1039/D1CC02937A

Abstract

The ABNO@PMO-IL-Br material obtained by anchoring 9-azabicyclo[3.3.1]nonane-3-one N-oxyl (keto-ABNO) within the mesopores of periodic mesoporous organosilica with bridged imidazolium groups is a robust bifunctional catalyst for the metal-free aerobic oxidation of numerous primary and secondary alcohols under oxygen balloon reaction conditions. The catalyst, furthermore, can be successfully employed in the first metal-free self-esterification of primary aliphatic alcohols affording valued esters.