Synthesis of thieno[2,3-c]acridine and furo[2,3-c]acridine derivatives via an iodocyclization reaction and their fluorescence properties and DFT mechanistic studies†,10.1039/C8NJ03511C

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Synthesis of thieno[2,3-c]acridine and furo[2,3-c]acridine derivatives via an iodocyclization reaction and their fluorescence properties and DFT mechanistic studies†

Amol D. Sonawane,Dinesh R. Garud,Taro Udagawa,Yasuhiro Kubota,Mamoru Koketsu

New Journal of Chemistry Pub Date : 08/10/2018 00:00:00 , DOI:10.1039/C8NJ03511C

Abstract

In this paper, we report the novel synthesis of thieno[2,3-c]acridine and furo[2,3-c]acridine derivatives via an intramolecular iodocyclization reaction. The thieno[2,3-c]acridine derivatives exhibited blue fluorescence in hexane. DFT and time-dependent (TD) DFT studies were carried out. This methodology provided a novel pathway to access thieno[2,3-c]acridine and furo[2,3-c]acridine derivatives via a 6-endo iodocyclization reaction.