960化工网
Synchronous architecture of ring-banded and non-ring-banded morphology within one spherulite based on in situ ring-opening polymerization of cyclic butylene terephthalate oligomers†
Jianqiang Zhang,Li Li,Senyang Song,Huixia Feng,Peng Chen,Zongbao Wang,Qun Gu
RSC Advances Pub Date : 09/28/2016 00:00:00 , DOI:10.1039/C6RA20471F
Abstract

Ring-banded morphology of polymerized cyclic butylene terephthalate (pCBT) accompanied by the synchronous evolution of non-ring-banded patterns was investigated for the first time through the crystallization of pCBT prepared by ring-opening polymerization (ROP) of cyclic butylene terephthalate oligomers (CBT). The result of gel permeation chromatography (GPC) shows that pCBT has a broader molecular weight distribution than commercial poly(butylene terephthalate) (PBT). The polar optical microscope (POM), atomic force microscopy (AFM) and scanning electron microscope (SEM) demonstrate that the ring-banded patterns originate from the lamellae twisting. The radial growth rates, in situ evolution and melting observation from the POM prove that the crystals' melting point in ring-bands is lower than that in non-ring-banded parts. And the crystals in ring-bands are deduced to be constructed by the low molecular weight pCBT fractions. Finally, the possible formation mechanism is discussed.

Graphical abstract: Synchronous architecture of ring-banded and non-ring-banded morphology within one spherulite based on in situ ring-opening polymerization of cyclic butylene terephthalate oligomers
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