Structure and reactivity of a novel parallel thiosulfito (SSO2-S∶S′) rhodium dinuclear complex
Kimie Shiomi,Brian K. Breedlove,Hiroaki Kitayama,Takanori Nishioka,Isamu Kinoshita,Nobuaki Koga,Kiyoshi Isobe
Chemical Communications Pub Date : 07/12/2002 00:00:00 , DOI:10.1039/B204765A
Abstract
The parallel thiosulfite ligand (SSO2) in a rhodium complex, which is formed by oxygenation of a bridging disulfide, is converted to a bridging hydrocarbyl thiolate ligand and sulfur dioxide gas by the reaction with hydrocarbyl halides.
