Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Criii hybrid inorganic–organic microporous solids: Criii(OH)·{O2C–C6H4–CO2}·{HO2C–C6H4–CO2H}x†
Franck Millange,Christian Serre,Gérard Férey
Chemical Communications Pub Date : 03/18/2002 00:00:00 , DOI:10.1039/B201381A
Abstract
The first three-dimensional chromium(III) dicarboxylate compounds have been isolated and their structures solved from powder X-ray diffraction data; the flexible framework of these materials delimits large pores.