Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane†‡
Nicole Harmgarth,Cristian G. Hrib,Volker Lorenz,Liane Hilfert,Frank T. Edelmann
Chemical Communications Pub Date : 09/10/2014 00:00:00 , DOI:10.1039/C4CC06261B
Abstract
An unprecedented deboronation reaction of icosahedral carboranes is described, in which a BH group of m-carborane is detached from the cage and incorporated into an unusual nido-carborane-anellated diazadiborepine ring system.