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Ag/white graphene foam for catalytic oxidation of methanol with high efficiency and stability†
Huijie Zhao,Xiufeng Song,Zhong Yan
Journal of Materials Chemistry A Pub Date : 02/05/2015 00:00:00 , DOI:10.1039/C4TA07053D
Abstract

Oxidation of methanol not only eliminates contamination due to typical volatile organic compounds (VOCs), but also provides clean energy. Here, we report Ag/white graphene foam to act as a catalyst for the oxidation reaction of methanol with both high conversion efficiency and high stability. The T50 and T95 of the Ag/white graphene foam catalyst are as low as 50 °C and 110 °C, almost half that of Ag/γ-Al2O3 catalysts. Furthermore, when the temperature was fixed at 100 °C, the 93% conversion efficiency of the Ag/white graphene foam was maintained with a fluctuation of less than 2% over 50 hours, while the conversion efficiency of Ag/γ-Al2O3 degraded sharply from 46% to 30%. Such outstanding catalytic performance of the Ag/white graphene foam is mainly attributed to the unique microstructure, especially the multi-level pores and few-layer atomically thin walls, which has been well confirmed by the SEM and TEM observations.

Graphical abstract: Ag/white graphene foam for catalytic oxidation of methanol with high efficiency and stability
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