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Versatile palladium-catalyzed C–H olefination of (hetero)arenes at room temperature†
Zhijie She,Yang Shi,Yumin Huang,Yangyang Cheng,Feijie Song,Jingsong You
Chemical Communications Pub Date : 09/17/2014 00:00:00 , DOI:10.1039/C4CC05827E
Abstract

The room-temperature oxidative C–H/C–H cross-couplings between (hetero)arenes and alkenes, coumarins or quinones have been reported by using a highly electrophilic palladium species [Pd(TFA)2], generated in situ from Pd(OAc)2 and TFA, as the catalyst and cheap (NH4)2S2O8 as the oxidant under air.

Graphical abstract: Versatile palladium-catalyzed C–H olefination of (hetero)arenes at room temperature
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