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Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties†
Makoto Saikawa,Takashi Nakamura,Junji Uchida,Masaki Yamamura,Tatsuya Nabeshima
Chemical Communications Pub Date : 07/21/2016 00:00:00 , DOI:10.1039/C6CC05439K
Abstract

A macrocyclic bisBODIPY (bis(boron-dipyrromethene)) complex [1B2] with a figure-of-eight helicity was synthesized and successfully resolved. [1B2] was proven to be one of the most efficient red-emitting CPL (circularly polarized luminescence) fluorophores reported to date (λ = 663 nm, |glum| = 9 × 10−3, ΦF = 0.58).

Graphical abstract: Synthesis of figure-of-eight helical bisBODIPY macrocycles and their chiroptical properties
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