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Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle†
José Vicente,María-Teresa Chicote,Miguel M. Alvarez-Falcón,Peter G. Jones
Chemical Communications Pub Date : 10/08/2004 00:00:00 , DOI:10.1039/B409921D
Abstract

trans-[Pt{C[triple bond, length as m-dash]C(Ar)C[triple bond, length as m-dash]CH}2(PMe3)2] (Ar = C6Me4-3,4,5,6) (1) reacts with PPN[Au(acac)2] (Hacac = acetylacetone; 1 ∶ 1.16 molar ratio; PPN = (Ph3P)2N) to give PPN[{Au{Pt(PMe3)2}2}{μ-Ar(C[triple bond, length as m-dash]C)2}3] (2) the crystal structure of which showed the anions as quasi equilateral triangles stacked parallel to each other through C–H⋯Au interactions, resulting in channels of rhombic cross-section.

Graphical abstract: Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle
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