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Synthesis of 6-substituted phenanthridines by metal-free, visible-light induced aerobic oxidative cyclization of 2-isocyanobiphenyls with hydrazines†
Tiebo Xiao,Linyong Li,Guoliang Lin,Qile Wang,Ping Zhang,Zong-wan Mao,Lei Zhou
Green Chemistry Pub Date : 01/29/2014 00:00:00 , DOI:10.1039/C3GC42517G
Abstract

Irradiation of hydrazines with visible-light in the presence of organic dye eosin B generates various types of functional radicals, which are trapped by 2-isocyanobiphenyls to give 6-substituted phenanthridines.

Graphical abstract: Synthesis of 6-substituted phenanthridines by metal-free, visible-light induced aerobic oxidative cyclization of 2-isocyanobiphenyls with hydrazines
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