In this work, we designed and synthesized four symmetric and asymmetric thienyl-substituted fluorenone compounds, which all exhibited typical AIE properties. Besides a high solid-state fluorescence quantum yield, the enhanced luminescence of their solid-state powders showed a 170 nm red-shift (from 380 to 550 nm) in comparison with the luminescence of their dilute tetrahydrofuran solutions. The photophysical properties and single-crystal structure, combined with the theoretical calculation, revealed that the bathochromic luminescence is due to the formation of static excimers.