An analogue of AlPO-CJ₂ microporous aluminophosphate containing heteroatomic Eu was hydrothermally synthesized in situ in the reactant system of carbamide–NH₄F–Al₂O₃–P₂O₅–H₂O, and characterization by ICP, powder XRD, Mössbauer spectra, ³¹P MAS NMR and luminescent spectroscopy prove that Eu is incorporated into the framework.