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Alkali metal-mediated dehydrocoupling of Me2NH·BH3†
Peter Bellham,Michael S. Hill,Gabriele Kociok-Köhn
Dalton Transactions Pub Date : 03/13/2015 00:00:00 , DOI:10.1039/C5DT00178A
Abstract

Bis(trimethylsilyl)amide derivatives of the group 1 elements (Li, Na, K) are competent pre-catalysts for the dehydrocoupling of Me2NH·BH3via the formation of intermediates containing [H3BNMe2BH2Me2N] anions.

Graphical abstract: Alkali metal-mediated dehydrocoupling of Me2NH·BH3
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