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The influence of ring strain on the formation of Si–H–Si stabilised oligosilanylsilyl cations†
Jelte P. Nimoth,Thomas Müller
Dalton Transactions Pub Date : 11/04/2021 00:00:00 , DOI:10.1039/D1DT03375A
Abstract

Hydride transfer between Si(SiMe2H)4 (2) and [Ph3C][B(C6F5)4] in 3-fluorotoluene yields the intermolecularly silane-stabilised silylium ion [((HMe2Si)3SiSiMe2)2H]+ ([5]+), independently of the amount of [Ph3C][B(C6F5)4] (0.5, 1.0 or 2.0 equiv.) used. The cyclic silane-stabilised silylium ion [4]+ is not detected by NMR spectroscopy. This result demonstrates the influence of ring strain effects on the formation of intra- ([4]+) or intermolecularly ([5]+) Si–H–Si bridged silyl cations.

Graphical abstract: The influence of ring strain on the formation of Si–H–Si stabilised oligosilanylsilyl cations
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