Alkyl isomerisation in three-coordinate iron(ii) complexes†
Javier Vela,Jeremy M. Smith,Rene J. Lachicotte,Patrick L. Holland
Chemical Communications Pub Date : 11/04/2002 00:00:00 , DOI:10.1039/B209389H
Abstract
The tertiary to iso-butyl isomerisation of three-coordinate iron(II) diketiminate complexes is reported and a hydride intermediate is proposed on the basis of exchange experiments.