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Synthesis of a novel strontium-based wide-bandgap semiconductor via X-ray photochemistry under extreme conditions†
Egor Evlyukhin,Eunja Kim,Petrika Cifligu,David Goldberger,Sarah Schyck,Blake Harris,Sindi Torres,George R. Rossman,Michael Pravica
Journal of Materials Chemistry C Pub Date : 11/02/2018 00:00:00 , DOI:10.1039/C8TC04496A
Abstract

The synthesis and characterization of a novel, low cost, amorphous wide-bandgap semiconductor via X-ray induced decomposition of strontium oxalate at high pressure have been demonstrated. By means of IR spectroscopy, the final product is identified as a mixture of strontium carbonate, strontium oxalate and CO-derived materials. Band gap measurements demonstrate that the final product exhibits a much lower band gap (2.45 eV) than the initial strontium oxalate powder (4.07 eV), suggesting that the synthesized material can be highly useful in electronic and optical applications.

Graphical abstract: Synthesis of a novel strontium-based wide-bandgap semiconductor via X-ray photochemistry under extreme conditions
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